Disc 1 : 1981-1983
- "I Don't Know (Live)" (Ozzy Osbourne, Randy Rhoads, Bob Daisley) – 5:02
- From Tribute
- "Mr. Crowley" (Ozzy Osbourne, Randy Rhoads, Bob Daisley) – 4:56
- From Blizzard of Ozz
- "Crazy Train" (Osbourne, Rhoads, Daisley) – 4:49
- From Blizzard of Ozz
- "Goodbye to Romance (Live)" (Osbourne, Rhoads, Daisley) – 5:24
- From Randy Rhoads Tribute
- "Suicide Solution (Live)" (Osbourne, Rhoads, Daisley) – 7:58
- From Tribute
- "Over the Mountain" (Osbourne, Rhoads, Daisley, Lee Kerslake) – 4:32
- From Diary of a Madman
- "Flying High Again (Live)" (Osbourne, Rhoads, Daisley, Kerslake) – 4:26
- From Tribute
- "You Can't Kill Rock and Roll" (Osbourne, Rhoads, Daisley, Kerslake) – 6:43
- From Diary of a Madman
- "Diary of a Madman" (Osbourne, Rhoads, Daisley, Kerslake) – 6:13
- From Diary of a Madman
- "Bark at the Moon (Live)" (Osbourne) – 4:23
- From B-Side of So Tired
- "Spiders in the Night" (Osbourne) – 4:28
- From Bark at the Moon
- "Rock 'n' Roll Rebel" (Osbourne) – 5:22
- From Bark at the Moon
- "You're No Different" (Osbourne) – 5:49
- From Bark at the Moon
Disc 2 : 1986-2001
- "The Ultimate Sin (Live)" (Osbourne, Jake E. Lee, Daisley) – 4:43
- From The Ultimate Ozzy video
- "Never Know Why (Live)" (Osbourne, Lee, Daisley) – 4:43
- From The Ultimate Ozzy video
- "Thank God for the Bomb (Live)" (Osbourne, Lee, Daisley) – 4:00
- From The Ultimate Ozzy video
- "Crazy Babies" (Osbourne, Zakk Wylde, Daisley, Randy Castillo) – 4:15
- From No Rest for the Wicked
- "Breakin' All the Rules" (Osbourne, Wylde, Daisley, Castillo, John Sinclair) – 5:12
- From No Rest for the Wicked
- "I Don't Want to Change the World (Demo)" (Osbourne, Wylde, Castillo, Lemmy) – 3:56
- From The No More Tears Demo Sessions
- "Mama, I'm Coming Home (Demo)" (Osbourne, Wylde, Lemmy) – 4:08
- From The No More Tears Demo Sessions
- "Desire (Demo)" (Osbourne, Wylde, Castillo, Lemmy) – 5:01
- From The No More Tears Demo Sessions
- "No More Tears" (Osbourne, Wylde, Mike Inez, Castillo, John Purdell) – 7:23
- From No More Tears
- "Won't Be Coming Home (S.I.N.) (Demo)" (Osbourne, Wylde, Castillo) – 4:59
- From The No More Tears Demo Sessions
- "Perry Mason (Live)" (Osbourne, Wylde, Purdell) – 5:56
- From Ozzfest 1
- "See You on the Other Side (Demo)" (Osbourne, Wylde, Lemmy) – 6:34
- Unreleased demo recorded during the No More Tears tour
- "Walk on Water (Demo)" (Osbourne, Jim Vallance) – 4:41
- From Beavis and Butt-head Do America OST
- "Gets Me Through (Live)" (Osbourne, Tim Palmer) – 4:28
- From Live at Budokan
- "Bang Bang (You're Dead)" (Osbourne, Palmer, Scott Humphrey, Geoff Nicholls) – 4:33
- Early version of "Facing Hell" from the Down to Earth sessions.
- "Dreamer" (Osbourne, Marti Frederiksen, Mick Jones) – 4:45
- From Down to Earth
Disc 3 : With Friends
- "Iron Man" (Osbourne, Tony Iommi, Geezer Butler, Bill Ward) – 5:26
- Ozzy Osbourne with Therapy?
- From 1994 in Nativity in Black tribute
- "N.I.B." (Osbourne, Iommi, Butler, Ward) – 5:58
- Ozzy Osbourne with Primus
- From 1999-2000 in Nativity in Black II tribute
- "Purple Haze" (Jimi Hendrix) – 4:22
- From 1989 in Stairway to Heaven/Highway to Hell compilation
- "Pictures of Matchstick Men" (Francis Rossi) – 6:02
- Ozzy Osbourne with Type O Negative
- From 1997 in Howard Stern - Private Parts OST
- "Shake Your Head (Let's Go To Bed)" (Don Was, David Was, Jarvis Stroud) – 3:55
- Ozzy Osbourne with Was (Not Was)
- From 1982-83 in Born to Laugh at Tornadoes album of Was (Not Was)
- "Born to Be Wild" (Mars Bonfire) – 3:29
- Ozzy Osbourne with Miss Piggy
- From 1994 in Kermit Unpigged compilation
- "Nowhere to Run (Vapor Trail)" (Osbourne, Earl Simmons, Jack Blades, John Eaton, Ken Jordan, Russell Jones, Rick Rubin, Scott Kirkland) – 4:44
- Ozzy Osbourne with The Crystal Method, DMX, Ol' Dirty Bastard & Fuzzbubble
- From 1998 in Chef Aid: The South Park Album OST
- "Psycho Man" (Osbourne, Iommi) – 5:18
- Black Sabbath
- From 1998 in Reunion
- "For Heaven's Sake 2000" (Osbourne, Iommi, Bob Marlette, Darryl Hill, Elgin Turner, Jason Hunter, Robert Diggs) – 4:57
- Ozzy Osbourne with Tony Iommi and Wu-Tang Clan
- From 1999 in Loud Rocks compilation
- "I Ain't No Nice Guy" (Lemmy) – 4:15
- Ozzy Osbourne with Motörhead and Slash
- From 1992 in March ör Die
- "Therapy" (Mike Muir, Robert Trujillo) – 3:25
- Ozzy Osbourne with Infectious Grooves
- From 1991 in The Plague That Makes Your Booty Move...It's the Infectious Grooves
- "Stayin' Alive" (Barry Gibb, Robin Gibb, Maurice Gibb) – 4:39
- Ozzy Osbourne with Dweezil Zappa
- "Dog, The Bounty Hunter" (Osbourne, Mark Hudson) – 0:53
Disc 4 : Under Covers
- "21st Century Schizoid Man" (Robert Fripp, Michael Giles, Greg Lake, Ian McDonald, Peter Sinfield) – 3:52
- King Crimson cover
- "Mississippi Queen" (Wes Golding) – 4:09
- Mountain cover
- "All The Young Dudes" (David Bowie) – 4:36
- Mott the Hoople cover
- "In My Life" (John Lennon, Paul McCartney) – 3:29
- The Beatles cover
- "Fire" (Arthur Brown, Vincent Crane, Mike Finesilver, Peter Ker) – 4:09
- The Crazy World of Arthur Brown cover
- "For What It's Worth" (Stephen Stills) – 3:20
- Buffalo Springfield cover
- "Sympathy for the Devil" (Mick Jagger, Keith Richards) – 7:12
- The Rolling Stones cover
- "Working Class Hero" (Lennon) – (3:24)
- John Lennon cover
- "Good Times" (Barry Jenkins, Daniel McCulloch, Eric Burdon, John Weider, Vic Briggs) – 3:46
- Eric Burdon & The Animals cover
- "Changes" (Osbourne, Iommi, Butler, Ward, Kelly Osbourne) – 4:06
- Ozzy Osbourne with Kelly Osbourne
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